Aims
This module provided an overview of some recent developments in the field of anion recognition and linked it to topics in supramolecular chemistry, biomedical applications and nanochemistry. The doctoral researchers gained insight into specific syntheses and modifications of anion receptors, their specific functions and their integration into functional materials with optimized catalytic activity and adjustable physical, magnetic, electronic, biological and optical properties.
Contents
Anion recognition chemistry has grown from its beginnings in the late 1960s and a variety of charged and neutral, cyclic and acyclic, inorganic and organic supramolecular host systems for the selective complexation, detection, and separation of anionic guest species have been developed. Recent developments include exciting advances in anion‐templated syntheses, directed self‐assembly, ion‐pair recognition, the function of anions in supramolecular catalysis, anion recognition in aqueous systems, fluorescence sensing of anion, recognition of anions in metal-organic frameworks. The two day module provided an introduction into the field and looked at then recent developments, covering anion recognition based on biomolecules, polymers, and nanoparticles.
Methods
- Synthesis of macrocyclic receptors
- anion as templates in synthesis
- macrocyclic chemistry
- molecular spectroscopy (fluorescence spectroscopy, IR, NMR, UV-Vis, etc.)
- Solution thermodynamics
- Structural changes due to anion binding
- calculations (quantum chemistry).
Recommendations for literature, e-learning
- P.D. Beer, P. A. Gale, Angew. Chem. Int. Ed. 2001, 40, 486-516
- Kataev, E. A., C. Müller (2014). Tetrahedron 2014, 70, 137-167.
- Responsible scientists: Berthold Kersting, Harald Krautscheid, Leipzig University
- Guest lecturers: Markus Albrecht (RWTH Aachen, Aachen, Germany), Anthony P. Davis (University of Bristol, Bristol, UK), Enrique García-España (Universidad de Valencia, Valencia, Spain), Evgeny Kataev (TU Chemnitz, Chemnitz, Germany), Stefan Kubik (TU Kaiserslautern), Carmelo Sgarlata (University of Catania, Italy)
- Date: September 20/21, 2018
- Time: 8:30-17:30/8:30-13:00
- Location: Faculty of Chemistry and Mineralogy, Johannisallee 29, SR102
- Language: English
Registration for the course has closed.
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